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固体氧化物燃料电池 8

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多目标自适应优化模型预测控制——降低氧化锌回转窑的碳排放 Article

Ke Wei, Keke Huang, Chunhua Yang, Weihua Gui

《工程（英文）》 2023年第27卷第8期页码 96-105 doi: 10.1016/j.eng.2023.01.017

摘要：

The zinc oxide rotary kiln, as an essential piece of equipment in the zinc smelting industrial process, is presenting new challenges in process control. China's strategy of achieving a carbon peak and carbon neutrality is putting new demands on the industry, including green production and the use of fewer resources; thus, traditional stability control is no longer suitable for multi-objective control tasks. Although researchers have revealed the principle of the rotary kiln and set up computational fluid dynamics (CFD) simulation models to study its dynamics, these models cannot be directly applied to process control due to their high computational complexity. To address these issues, this paper proposes a multi-objective adaptive optimization model predictive control (MAO-MPC) method based on sparse identification. More specifically, with a large amount of data collected from a CFD model, a sparse regression problem is first formulated and solved to obtain a reduction model. Then, a two-layered control framework including real-time optimization (RTO) and model predictive control (MPC) is designed. In the RTO layer, an optimization problem with the goal of achieving optimal operation performance and the lowest possible resource consumption is set up. By solving the optimization problem in real time, a suitable setting value is sent to the MPC layer to ensure that the zinc oxide rotary kiln always functions in an optimal state. Our experiments show the strength and reliability of the proposed method, which reduces the usage of coal while maintaining high profits.

关键词： Zinc oxide rotary kiln Model reduction Sparse identification Real-time optimization Model predictive control Process control

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Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

《环境科学与工程前沿（英文）》 2022年第16卷第7期 doi: 10.1007/s11783-021-1488-1

摘要：

• Adding kaolin/zeolite promotes the formation of stable heavy metals.

关键词： Co-pyrolysis Sewage sludge Heavy metals Rotary kiln Immobilization mechanism

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Templated synthesis of urchin-like zinc oxide particles by micro-combustion

Xintong ZHOU, Quan ZHANG, Chang-jun LIU

《化学科学与工程前沿（英文）》 2014年第8卷第1期页码 73-78 doi: 10.1007/s11705-014-1404-3

摘要： Micro-combustion initiated by dielectric barrier discharge plasma has been applied for the removal of carbon template to prepare urchin-like ZnO particles. The combustion is operated at atmospheric pressure and low gas temperature (less than 150 °C), and the template is fully decomposed and rapidly removed. The obtained urchin-like ZnO possesses two distinct morphologies: nanosheets and sub-micro rods. The unique morphologies form on ZnO hexagonal nuclei with the template effect of activated carbon.

关键词： dielectric-barrier discharge zinc oxide carbon template removal plasma

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物料与窑壁间歇接触对回转窑传热过程的强化效应

雷先明,肖友刚

《中国工程科学》 2006年第8卷第8期页码 39-44

摘要：

根据回转窑内物料颗粒的运动特点，推导了颗粒团在贴壁运动过程中的非稳态导热系数及界面处的接触传热系数，进而得出了物料与封盖窑壁间的换热系数；结合已有研究成果，建立了回转窑的传热数学模型。计算表明，未考虑物料与窑壁间歇接触对回转窑传热过程的强化效应时，物料温度偏低；温度越高，强化效应对物料温度的影响越大；考虑物料与窑壁间歇接触对回转窑传热过程的强化效应，有利于提高回转窑煅烧熟料的质量和热效率。

关键词：物料封盖传热过程强化效应

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Ecotoxicological effect of zinc oxide nanoparticles on soil microorganisms

Zhaoyi SHEN,Zhuo CHEN,Zhen HOU,Tingting LI,Xiaoxia LU

《环境科学与工程前沿（英文）》 2015年第9卷第5期页码 912-918 doi: 10.1007/s11783-015-0789-7

摘要： The widespread production and use of zinc oxide nanoparticles (ZnO-NPs) in recent years have posed potential threat to the ecosystem. This study aimed to investigate the ecotoxicological effect of ZnO-NPs on soil microorganisms using laboratory microcosm test. Respiration, ammonification, dehydrogenase (DH) activity, and fluorescent diacetate hydrolase (FDAH) activity were used as ecotoxicological parameters. The results showed that in the neutral soil treated with 1 mg ZnO-NPs per g soil (fresh, neutral), ammonification was significantly inhibited during the study period of three months, but the inhibition rate decreased over increasing time. Inhibition in respiration was observed in the first month of the test. In various ZnO-NPs treatments (1 mg, 5 mg, and 10 mg ZnO-NPs per g soil), DH activity and FDAH activity were inhibited during the study period of one month. For both enzyme activities, there were positive dose–response relationships between the concentration of ZnO-NPs and the inhibition rates, but the curves changed over time due to changes of ZnO-NPs toxicity. Soil type affected the toxicity of ZnO-NPs in soil. The toxicity was highest in the acid soil, followed by the neutral soil. The toxicity was relatively low in the alkaline soil. The toxicity was not accounted for by the Zn released from the ZnO-NPs. Direct interaction of ZnO-NPs with biologic targets might be one of the reasons. The adverse effect of ZnO-NPs on soil microorganisms in neutral and acid soils is worthy of attention.

关键词： zinc oxide nanoparticles (ZnO-NPs) soil microorganisms respiration ammonification dehydrogenase (DH) activity fluorescent diacetate hydrolase (FDAH) activity

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Vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coatingfor high performance zinc-ion batteries

《化学科学与工程前沿（英文）》 2023年第17卷第9期页码 1244-1253 doi: 10.1007/s11705-022-2293-5

摘要： Vanadium oxides as cathode for zinc-ion batteries have attracted much attention because of their high theoretical capacity, flexible layered structure and abundant resources. However, cathodes are susceptible to the collapse of their layered structure and the dissolution of vanadium after repeated long cycles, which worsen their capacities and cycling stabilities. Herein, a synergistic engineering of calcium-ion intercalation and polyaniline coating was developed to achieve the superior electrochemical performance of vanadium pentoxide for zinc-ion batteries. The pre-intercalation of calcium-ion between vanadium pentoxide layers as pillars increase the crystal structure’s stability, while the polyaniline coating on the cathodes improves the conductivity and inhibits the dissolution of vanadium. This synergistic engineering enables that the battery system based-on the polyaniline coated calcium vanadate cathode to deliver a high capacity of 406.4 mAh·g⁻¹ at 1 A·g⁻¹, an ultralong cycle life over 6000 cycles at 10 A·g⁻¹ with 93% capacity retention and high-rate capability. The vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coating was verified to effectively improve the electrochemical performance of zinc-ion batteries.

关键词： zinc-ion battery CaV₈O₂₀ polyaniline coating synergistic engineering high capacity long durability

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Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison

《化学科学与工程前沿（英文）》 2023年第17卷第6期页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要： The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词： bio-based multifunction colorimetric indicator active and intelligent packaging

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Biotoxicity evaluation of zinc oxide nanoparticles on bacterial performance of activated sludge at COD

《环境科学与工程前沿（英文）》 2022年第16卷第2期 doi: 10.1007/s11783-021-1453-z

摘要：

• ZnO-NP disrupted metabolic/catabolic balance of bacteria by affecting DHA activity.

关键词： Granular sludge Biotoxicity Reactive oxygen species Extracellular polymeric substances

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Dynamic changes of protein corona compositions on the surface of zinc oxide nanoparticle in cell culture

Vo-Van Giau, Yoon-Hee Park, Kyu-Hwan Shim, Sang-Wook Son, Seong-Soo A. An

《化学科学与工程前沿（英文）》 2019年第13卷第1期页码 90-97 doi: 10.1007/s11705-018-1766-z

摘要：

The potential applications of nanomaterials used in nanomedicine as ingredients in drug delivery systems and in other products continue to expand. When nanomaterials are introduced into physiological environments and driven by energetics, they readily associate proteins forming a protein corona (PC) on their surface. This PC could result in an alteration of the nanomaterial’s surface characteristics, affecting their interaction with cells due to conformational changes in adsorbed protein molecules. However, our current understanding of nanobiological interactions is still very limited. Utilizing a liquid chromatography–mass spectroscopy/mass spectroscopy technology and a Cytoscape plugin (ClueGO) approach, we examined the composition of the PC for a set of zinc oxide nanoparticles (ZnONP) from cell culture media typically and further analyzed the biological interaction of identified proteins, respectively. In total, 36 and 33 common proteins were investigated as being bound to ZnONP at 5 min and 60 min, respectively. These proteins were further analyzed with ClueGO, a Cytoscape plugin, which provided gene ontology and the biological interaction processes of identified proteins. Proteins bound to the surface of nanoparticles that may modify the structure, therefore the function of the adsorbed protein could be consequently affect the complicated biological processes.

关键词： ZnONPs nanoparticles protein corona ClueGO

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大型多支承回转窑托轮偏斜接触有限元分析

李学军,张美阳,褚福磊

《中国工程科学》 2007年第9卷第12期页码 16-20

摘要：

针对回转窑托轮偏斜对接触区应力分布的影响，运用赫兹接触理论，推导出托轮与滚圈最大接触应力比与托轮偏斜角的关系；采用有限元方法计算某支承结构托轮平行与呈最大偏斜角时的接触问题，得到支承部件接触应力和等效应力应变分布情况，并得出滚圈和托轮的危险易损部位；为回转窑的轴向调控提供了有效的理论依据。

关键词：大型多支承托轮偏斜接触应力有限元

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碱式碳酸锌热分解机理及动力学

马正先,韩跃新,刘春生,郑龙熙,王泽红

《中国工程科学》 2003年第5卷第10期页码 78-82

摘要：

采用TG、DTA、DTG等热分析手段研究了碱式碳酸锌热分解过程，热分析研究结果显示, Zn₅(CO₃)₂·(OH)₆为一步分解而得到纳米氧化锌，研究得到的机理模型证明其热分解过程符合随机核化机理。利用XRD，TEM等测试手段对纳米氧化锌的结构和形貌进行了表征，结果表明，通过Zn₅(CO₃)₂·(OH)₆热分解方法可以获得结晶性及分散性良好、粒径分布窄、粒度约为10nm左右的纳米氧化锌。

关键词：纳米氧化锌碱式碳酸锌机理动力学热分解

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Alumina modified sodium vanadate cathode for aqueous zinc-ion batteries

《能源前沿（英文）》页码 775-781 doi: 10.1007/s11708-023-0902-8

摘要： Aqueous zinc-ion batteries (ZIBs) have great prospects for widespread application in massive scale energy storage. By virtue of the multivalent state, open frame structure and high theoretical specific capacity, vanadium (V)-based compounds are a kind of the most developmental potential cathode materials for ZIBs. However, the slow kinetics caused by low conductivity and the capacity degradation caused by material dissolution still need to be addressed for large-scale applications. Therefore, sodium vanadate Na₂V₆O₁₆·3H₂O (NVO) was chosen as a model material, and was modified with alumina coating through simple mixing and stirring methods. After Al₂O₃ coating modification, the rate capability and long-cycle stability of Zn//NVO@Al₂O₃ battery have been significantly improved. The discharge specific capacity of NVO@Al₂O₃ reach up to 228 mAh/g (at 4 A/g), with a capacity reservation rate of approximately 68% after 1000 cycles, and the Coulombic efficiency (CE) is close to 100%. As a comparison, the capacity reservation rate of Zn//NVO battery is only 27.7%. Its superior electrochemical performance is mainly attributed to the Al₂O₃ coating layer, which can increase zinc-ion conductivity of the material surface, and to some extent inhibit the dissolution of NVO, making the structure stable and improving the cyclic stability of the material. This paper offers new prospects for the development of cathode coating materials for ZIBs.

关键词： cathodes aqueous zinc-ion batteries sodium vanadate alumina coating

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Zinc homeostasis in the metabolic syndrome and diabetes

null

《医学前沿（英文）》 2013年第7卷第1期页码 31-52 doi: 10.1007/s11684-013-0251-9

摘要：

Zinc (Zn) is an essential mineral that is required for various cellular functions. Zn dyshomeostasis always is related to certain disorders such as metabolic syndrome, diabetes and diabetic complications. The associations of Zn with metabolic syndrome, diabetes and diabetic complications, thus, stem from the multiple roles of Zn: (1) a constructive component of many important enzymes or proteins, (2) a requirement for insulin storage and secretion, (3) a direct or indirect antioxidant action, and (4) an insulin-like action. However, whether there is a clear cause-and-effect relationship of Zn with metabolic syndrome, diabetes, or diabetic complications remains unclear. In fact, it is known that Zn deficiency is a common phenomenon in diabetic patients. Chronic low intake of Zn was associated with the increased risk of diabetes and diabetes also impairs Zn metabolism. Theoretically Zn supplementation should prevent the metabolic syndrome, diabetes, and diabetic complications; however, limited available data are not always supportive of the above notion. Therefore, this review has tried to summarize these pieces of available information, possible mechanisms by which Zn prevents the metabolic syndrome, diabetes, and diabetic complications. In the final part, what are the current issues for Zn supplementation were also discussed.

关键词： zinc zinc transporters metallothionein diabetes diabetic complications insulin resistance antioxidant

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Copper and zinc interaction on water clearance and tissue metal distribution in the freshwater mussel

Tianxiang XIA, Xuehua LIU

《环境科学与工程前沿（英文）》 2011年第5卷第2期页码 236-242 doi: 10.1007/s11783-010-0218-8

摘要： Copper and zinc interaction on clearance from water and distribution in different tissues was investigated for the freshwater mussel, , under laboratory conditions. Clearance rate of Cu or Zn from water was highly dependent on exposure concentration. Interaction effect was most evident at 300 μg·L Cu exposure and depressed the Zn clearance rate significantly ( <0.05). However, the presence of 100 μg·L and 300 μg·L Zn hardly affected the Cu clearance rate. The 300 μg·L Cu presence enhanced Cu accumulation in each tissue most significantly ( <0.01), but caused Zn content to decrease in the gills by 62% ( <0.05), viscera by 49% ( <0.05) and foot by 31% ( <0.05), and increase in the mantle by 97% ( <0.05) and the muscles by 243% ( <0.05) for different Zn exposure treatments. The response of metal accumulation in various tissues of the test mussels indicated that Zn transferred from the gills, viscera and foot to the mantle and muscles might be one of the important characteristics of the Zn regulatory mechanism by leading to a narrow range of Zn concentration in the different tissues.

关键词： interaction mussel copper zinc clearance distribution

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Soybean drying characteristics in microwave rotary dryer with forced convection

Ruifang WANG, Zhanyong LI, Yanhua LI, Jingsheng YE

《化学科学与工程前沿（英文）》 2009年第3卷第3期页码 289-292 doi: 10.1007/s11705-009-0022-y

摘要： A new hybrid drying technique by combining microwave and forced convection drying within a rotary drum, i.e., microwave rotary drying, was developed with the purpose to improve the uniformity of microwave drying. In a laboratory microwave rotary dryer, rewetted soybean was utilized as experimental material to study the effects of drum rotating speed, ventilation flow rate, and specific microwave power on the drying kinetics and cracking ratio of soybean. It was found that, with rotation, the cracking ratio can be lowered but without distinct improvement in the drying rate. Increasing ventilation flow rate and specific microwave power can improve the drying rate, but the cracking ratio also increases as a negative result. The cracking ratio lower than 10% can be attained for ventilation flow rate lower than 2.0 m ·h or specific microwave energy lower than 0.4 kW·kg in the present experiments.

关键词： cracking microwave rotary drying soybean